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Prem (Salman Khan) is a Love Guru who solves the love issues of his clients. He meets Bhaskar Diwakar Chaudhary (Govinda) who comes to Prem for help in his love life. Bhaskar loves his boss Priya Jaisingh (Katrina Kaif) but is unable to express his love to her as she is the daughter of a wealthy businessman. Prem initially refuses to help Bhaskar and goes to Phuket, Thailand. Bhaskar follows him there and convinces him to help.
After returning from Thailand, Prem meets Naina (Lara Dutta), a photo journalist who was running from some gangsters led by Chhota Don (Rajpal Yadav), who mimicks Shahrukh Khan in Don. Prem saves her and falls in love with her. Meanwhile, he starts teaching Bhaskar how to impress Priya. But Bhaskar uses his own simplicity and nonsense acts to impress Priya. Priya finally falls in love with Bhaskar but does not disclose it to him.
- Govinda as Bhaskar Devakar Chaudhary, A nerdy man who has a crush on his boss Priya Jaisingh.
- Salman Khan as Prem (Love Guru), A love master who gives advice to those who need help getting people in love.
- Lara Dutta as Naina
- Katrina Kaif as Priya Jaisingh
- Master Ali Haji as Rohan (Naina's son)
- Dalip Tahil as Raj Jaisingh
- Aarti Chabria as Nikki (Naina's colleague)
- Rajat Bedi as Neil Bakshi
- Suresh Menon as Kiran
- Deepshikha as Pammi, Prem's sister
- Tiku Talsania as Naina's boss
- Ali Asgar as Naina's colleague
- Atul Parchure as a Police Officer
- Vindu Dara Singh as Chadha
- Razak Khan as John uncle
- Puneet Issar as Rana
- Rajpal Yadav as Chhota Don
- Shashi Kiran as Newspaper stall owner
- Dheirya Sorecha as Pammi's son
- Jason Shah as Priya's fiancé